Process Tools

Crystallization

Theory

Crystallization Calculator

Design batch and continuous crystallizers with yield and purity calculations

Input Parameters

Concentration at starting temperature

Must be less than initial concentration

Accounts for losses and incomplete crystallization

Typical range: 10⁻⁹ to 10⁻⁷ m/s

Quick Reference

  • • Cooling: Lower temperature reduces solubility
  • • Evaporative: Remove solvent to increase concentration
  • • Higher supersaturation = faster crystallization
  • • Slower cooling = larger, purer crystals

Crystallization Results

Theoretical Yield
66.7%
153.8 kg
Actual Yield
56.7%
130.8 kg

Process Parameters

Crystal Mass:130.77 kg
Mother Liquor:869.2 L
Supersaturation Ratio:3.00
Crystal Purity:96.7%
MSZW Estimate:20.00 g/100g

MSMPR Continuous Crystallizer

Residence Time:13.89 hours
(50000 seconds)
Production Rate:130.8 kg/batch

Based on 500 μm dominant crystal size

Design Recommendations

  • ⚠ High supersaturation - may cause rapid nucleation and small crystals
  • ⚠ Low yield - consider lower final temperature
  • • Consider seeding to control crystal size distribution

Solubility Curve

Solubility vs Temperature

Initial
30g
Final
10g
Supersaturated region

The difference between initial concentration and final solubility determines the maximum theoretical yield. Operating within the metastable zone (MSZW) prevents excessive nucleation.

Learn More

Understand the principles of crystallization, nucleation, crystal growth, and process design strategies.

View Theory & Examples